Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys

Salim Ali Mohammad; Samiea Yaseen Sharaf Zeebaree

doi:doi:10.11648/j.sjc.20170506.12

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Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys

Salim Ali Mohammad, Samiea Yaseen Sharaf Zeebaree

Published in Science Journal of Chemistry (Volume 5, Issue 6)

Received: 18 October 2017 Accepted: 6 November 2017 Published: 29 November 2017

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Abstract

An easy, accurate, selective and sensitive method for extraction and spectrophotometric determination of yttrium (III) in aqueous solution has been determined. The procedure is based on the extract of yttrium (III) with Trioctylphosphine oxide (TOPO) reagent from the aqueous medium followed reaction of extracted yttrium (III) in organic layer with alizarin red s (ARS) reagent at pH 4.9 to form a red carmine complex which has maximum absorption at 519 nm. Beer's law is obeyed over the concentration range 10-260 µg yttrium (III) /10 ml, (i. e., 1-26 ppm) with a determination coefficient of (0.991) and molar absorptivity of 0.53×10⁴ l.mol^-1.cm^-1. The recoveries are obtained in the range of 98.7 - 100.01% and a relative standard deviation is better than ±2.33%. The method has been successfully applied to the determination of yttrium (III) in natural waters and magnesium alloys.

Published in	Science Journal of Chemistry (Volume 5, Issue 6)
DOI	10.11648/j.sjc.20170506.12
Page(s)	80-86
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Yttrium (III), Extraction, TOPO, Spectrophotometric, Alloys

References

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[4]	E., Steinnes, O., R., Birkelund, O., Johansen, (1971), Determination of trace element in biological material by neutron activation and extraction with TOPO, journal of radioanalytical chemistry, 9, 267-272.
[5]	M., Yamada, S., Kusakabe, J., Prekopova And T., Sekine, (1996), Solvent Extraction of Seven Trivalent Metal Ions in Aqueous Perchlorate Solutions with Trioctylphosphine Oxide in Hexane and Rapid Extraction of Chromium (III), Analytical science, 12, 405.
[6]	T., A., Butler, E., E., Ketchen, (1961), Solvent Extraction Separation of Cerium and Yttrium from Other Rare Earth Fission Products, Industrial and engineering chemistry, 53(8), 651-654.
[7]	W., Li, X., Wang, H., Zhang, S., Meng, D., Li, (2007), Solvent extraction of lanthanides and yttrium from nitrate medium with cyanex 925 in heptane, Chemical technology and biotechnology, 82(4), 376-381.
[8]	B., Gupta, P., Malak and A., Deep, (2003), Solvent extraction and separation of tervalent lanthanides and yttrium using cyanix 923, solvent extraction and ion exchange, 21(2), 239-258.
[9]	W., Wei, L., Yu, X., Aimei, Y., Hualing, C., Hongmin and C., Ji, (2012), Solvent extraction of yttrium by task –specific ionic liquid bearing carboxylic group, Chinese journal of chemical engineering, 20(1), 40-46.
[10]	D., D., Perrin, B., Dempsy, 1974. Buffers for pH and metal Ion Control. Champan and Hall Ltd., London, 132.
[11]	International Conference on Harmonization (2005), ICH Harmonized Tripartite Guide-line: Validation of Analytical Procedures Text and Methodology, Q2 (R1), Current Step 4 Version, 11-13.
[12]	Henriksen, A., 1965. An Automatic Method for Determining Nitrate and Nitrite in Fresh and Saline Waters, Analyst, 90, 83-88.
[13]	https://en.wikipedia.org/wiki/Magnesium_alloy/ (accessed 15 April 2015).
[14]	B., N., Kokare, A., M., Mandthare, S., S., Kolekar and M., A., Anuse, N-n-octylaniline as a New reagent for analytical Liqiud-liqiud extraction of yttrium (III) from matrices of various metal ions, Macedonian Journal of Chemistry and Chemical Engineering, (2011), 30 (2) p. 151-162.

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APA Style

Salim Ali Mohammad, Samiea Yaseen Sharaf Zeebaree. (2017). Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys. Science Journal of Chemistry, 5(6), 80-86. https://doi.org/10.11648/j.sjc.20170506.12

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ACS Style

Salim Ali Mohammad; Samiea Yaseen Sharaf Zeebaree. Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys. Sci. J. Chem. 2017, 5(6), 80-86. doi: 10.11648/j.sjc.20170506.12

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AMA Style

Salim Ali Mohammad, Samiea Yaseen Sharaf Zeebaree. Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys. Sci J Chem. 2017;5(6):80-86. doi: 10.11648/j.sjc.20170506.12

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@article{10.11648/j.sjc.20170506.12,
  author = {Salim Ali Mohammad and Samiea Yaseen Sharaf Zeebaree},
  title = {Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys},
  journal = {Science Journal of Chemistry},
  volume = {5},
  number = {6},
  pages = {80-86},
  doi = {10.11648/j.sjc.20170506.12},
  url = {https://doi.org/10.11648/j.sjc.20170506.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20170506.12},
  abstract = {An easy, accurate, selective and sensitive method for extraction and spectrophotometric determination of yttrium (III) in aqueous solution has been determined. The procedure is based on the extract of yttrium (III) with Trioctylphosphine oxide (TOPO) reagent from the aqueous medium followed reaction of extracted yttrium (III) in organic layer with alizarin red s (ARS) reagent at pH 4.9 to form a red carmine complex which has maximum absorption at 519 nm. Beer's law is obeyed over the concentration range 10-260 µg yttrium (III) /10 ml, (i. e., 1-26 ppm) with a determination coefficient of (0.991) and molar absorptivity of 0.53×104 l.mol-1.cm-1. The recoveries are obtained in the range of 98.7 - 100.01% and a relative standard deviation is better than ±2.33%. The method has been successfully applied to the determination of yttrium (III) in natural waters and magnesium alloys.},
 year = {2017}
}

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TY  - JOUR
T1  - Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys
AU  - Salim Ali Mohammad
AU  - Samiea Yaseen Sharaf Zeebaree
Y1  - 2017/11/29
PY  - 2017
N1  - https://doi.org/10.11648/j.sjc.20170506.12
DO  - 10.11648/j.sjc.20170506.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 80
EP  - 86
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20170506.12
AB  - An easy, accurate, selective and sensitive method for extraction and spectrophotometric determination of yttrium (III) in aqueous solution has been determined. The procedure is based on the extract of yttrium (III) with Trioctylphosphine oxide (TOPO) reagent from the aqueous medium followed reaction of extracted yttrium (III) in organic layer with alizarin red s (ARS) reagent at pH 4.9 to form a red carmine complex which has maximum absorption at 519 nm. Beer's law is obeyed over the concentration range 10-260 µg yttrium (III) /10 ml, (i. e., 1-26 ppm) with a determination coefficient of (0.991) and molar absorptivity of 0.53×104 l.mol-1.cm-1. The recoveries are obtained in the range of 98.7 - 100.01% and a relative standard deviation is better than ±2.33%. The method has been successfully applied to the determination of yttrium (III) in natural waters and magnesium alloys.
VL  - 5
IS  - 6
ER  -

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Author Information

Salim Ali Mohammad

Department of Chemistry, College of Science, Mosul University, Mosul, Iraq
Samiea Yaseen Sharaf Zeebaree

Department of Chemistry, College of Science, Mosul University, Mosul, Iraq

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APA Style

Salim Ali Mohammad, Samiea Yaseen Sharaf Zeebaree. (2017). Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys. Science Journal of Chemistry, 5(6), 80-86. https://doi.org/10.11648/j.sjc.20170506.12

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ACS Style

Salim Ali Mohammad; Samiea Yaseen Sharaf Zeebaree. Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys. Sci. J. Chem. 2017, 5(6), 80-86. doi: 10.11648/j.sjc.20170506.12

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AMA Style

Salim Ali Mohammad, Samiea Yaseen Sharaf Zeebaree. Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys. Sci J Chem. 2017;5(6):80-86. doi: 10.11648/j.sjc.20170506.12

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@article{10.11648/j.sjc.20170506.12,
  author = {Salim Ali Mohammad and Samiea Yaseen Sharaf Zeebaree},
  title = {Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys},
  journal = {Science Journal of Chemistry},
  volume = {5},
  number = {6},
  pages = {80-86},
  doi = {10.11648/j.sjc.20170506.12},
  url = {https://doi.org/10.11648/j.sjc.20170506.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20170506.12},
  abstract = {An easy, accurate, selective and sensitive method for extraction and spectrophotometric determination of yttrium (III) in aqueous solution has been determined. The procedure is based on the extract of yttrium (III) with Trioctylphosphine oxide (TOPO) reagent from the aqueous medium followed reaction of extracted yttrium (III) in organic layer with alizarin red s (ARS) reagent at pH 4.9 to form a red carmine complex which has maximum absorption at 519 nm. Beer's law is obeyed over the concentration range 10-260 µg yttrium (III) /10 ml, (i. e., 1-26 ppm) with a determination coefficient of (0.991) and molar absorptivity of 0.53×104 l.mol-1.cm-1. The recoveries are obtained in the range of 98.7 - 100.01% and a relative standard deviation is better than ±2.33%. The method has been successfully applied to the determination of yttrium (III) in natural waters and magnesium alloys.},
 year = {2017}
}

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TY  - JOUR
T1  - Extraction and Spectrophotometric Assay of Yttrium (III) with TOPO, Application to Water Samples and Alloys
AU  - Salim Ali Mohammad
AU  - Samiea Yaseen Sharaf Zeebaree
Y1  - 2017/11/29
PY  - 2017
N1  - https://doi.org/10.11648/j.sjc.20170506.12
DO  - 10.11648/j.sjc.20170506.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 80
EP  - 86
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20170506.12
AB  - An easy, accurate, selective and sensitive method for extraction and spectrophotometric determination of yttrium (III) in aqueous solution has been determined. The procedure is based on the extract of yttrium (III) with Trioctylphosphine oxide (TOPO) reagent from the aqueous medium followed reaction of extracted yttrium (III) in organic layer with alizarin red s (ARS) reagent at pH 4.9 to form a red carmine complex which has maximum absorption at 519 nm. Beer's law is obeyed over the concentration range 10-260 µg yttrium (III) /10 ml, (i. e., 1-26 ppm) with a determination coefficient of (0.991) and molar absorptivity of 0.53×104 l.mol-1.cm-1. The recoveries are obtained in the range of 98.7 - 100.01% and a relative standard deviation is better than ±2.33%. The method has been successfully applied to the determination of yttrium (III) in natural waters and magnesium alloys.
VL  - 5
IS  - 6
ER  -

Copy | Download